The work of
group for the search of novel crystalline materials are
held at M.V. Lomonosov Moscow State University since
1964. The main aim of investigations are search and
study of new promising multifunctional materials with
unusual physical properties: ferroelectrics, superionic
conductors, nonlinear optical materials, laser crystals,
piezoelectrics, etc. At the same time a fundamental
problem of interactions between composition, structure
and properties is solved.
More than 200 different oxide materials were synthesized
and studied in the our group. Among them there are three
family of ferroelectrics (hexagonal tungsten bronzes,
defective pyroclor, KTiOPO4-family),
high-temperature superconductor YBa2Cu3Ox,
oxygen conductors from LAMOX family (based on La2Mo2O9),
mixed-layer and ordinary Aurivillius phases. Many
compounds have been obtained and investigated for the
first time.
At present, the group is interested in search and study
of new crystalline materials with high ionic
conductivity for the new energy, mainly, compounds with
high oxygen conductivity.
Since 1981 the laboratory conducted intensive studies on
the crystallization processes. New interferometric
techniques was the first that allowed measurement of the
morphology of the growing crystal face simultaneously
with measuring the growth conditions for quantitative
check of the contemporary theory of layer-by-layer
spiral crystal growth. Basic growth parameters
controlling the growth, free step energy, step kinetic
coefficient, were investigated. Dislocation activity was
measured for the first time. Applying atomic force
microscopy to study growth of lysozyme crystals allowed
for the first time to observe a single-lattice-parameter
deep kink on an elemental step. Violation of the Gibbs-
Thomson law was discovered.
Technique of fast crystal growth from solutions was
initiated and developed.
For a long time, the laboratory involved in growing,
research and application properties of lithium niobate
crystals with periodic domain structure. These crystals
are increasingly used for quasisynchronous conversion of
laser radiation, including in the terahertz range.
Possible to obtain crystals with extensive equidistant
growth layers in which the spontaneous polarization
changes sign. |